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MPXM2102AS 数据表(PDF) 26 Page - Motorola, Inc |
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MPXM2102AS 数据表(HTML) 26 Page - Motorola, Inc |
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26 / 670 page ![]() 1–20 Motorola Sensor Device Data www.motorola.com/semiconductors “C” is intended to swell polymeric materials. Contaminants in actual gasoline can result in corrosion or material degradation, so chloride ions or formic acid with distilled water are added to create an aggressive fuel media. Gasoline can decompose by a process called auto–oxidation that will form aggressive substances that can dissolve polymers or corrode metal. Copper is added as a trace metal to accelerate the formation of free radicals from the hydroperoxides. Table 2 details the various gasoline/methanol mixtures with additives recommended by the task force from Chrysler, Ford, and General Motors. Table 2. Fuel Testing Methods Elastomer Polymer Metal Alcohol/Fuel Blends CMO CMO CM15 CM15 CM15 CM30 CM30 CM50 CM50 CM85 CM85 CM85 Aggressive Fuel, Add Chloride ion Distilled water Formic Acid Chloride ion Sodium Chloride Formic Acid Auto Oxidized Fuels, Add t–Butyl Hydroperoxide t–Butyl Hydroperoxide Cu+ Recommended gasoline/methanol mixtures for material testing. The recommended testing for metals should include immersion in the liquid as well as exposure to the vapor. The coding for the alcohol/fuel blends, CMxx is: C for Fuel C; M for methanol; and xx indicating the percentage of methanol in the mixture. The general question for the appliance industry compatibility issues is not whether the media will contain ions (as it most assuredly will) but at what concentration. Tap water with no alkali additives contains ions capable of contributing to a corrosive reaction [14]. A typical application of a pressure sensor in the appliance industry is sensing the water level in a washing machine. The primary ingredients of detergent used in a washing machine are: surfactants, builders, whitening agents and enzymes [15]. The surfactants dissolve dirt and emulsify oil, grease and dirt. They can be anionic or cationic. Cationic surfactants are present in detergent–softener combinations. Builders or alkaline water conditioning agents are added to the detergent to soften the water, thus increasing the efficiency of the surfactant. These builders maintain alkalinity that results in improved cleaning. Alkaline solutions at temperatures indicated by the appliance industry range can etch bare silicon similar to the bulk micromachining process. Thus bare silicon could be adversely affected by exposure to these liquids [16]. FAILURE MECHANISMS The failure mechanisms that can affect sensors and actuators are similar to that for electronic devices. These failure mechanisms provide a means of categorizing the varIous effects caused by chemical, mechanical, electrical, and thermal environments encountered. An understanding of the potential failure mechanisms should be determined before media testing begins. The typical industry scenario has been to follow a set boiler plate of tests and then determine reliability. This may have been acceptable for typical electronic devices, but the applications for sensors are more demanding of a thorough understanding before testing begins. The sensitivity of the device to its physical environment is heightened for a pressure sensor. Any change in the material properties results in a change of the sensor performance. Failure mechanisms for pressure sensors in harsh media application are listed below. The pressure sensor allows a format for discussion, though the mechanisms discussed are applicable in some degree to all sensor and actuator devices. Corrosion Corrosion has been defined as any destructive result of a chemical reaction between a metal or metal alloy and its environment [17]. Several metal surfaces exist within a pressure sensor package: metallic lines on the die, trimmable resistors, bonding pads, wires, leadframes, etc. Much of the die–level metal is protected by an overlying inorganic passivation material (e.g., PECVD silicon nitride); however, unless some package–level encapsulant is used, bondpads, wires, and leadframes are exposed to the harsh media and are potential corrosion sites. Furthermore, an energized pressure sensor has a voltage difference between these exposed metallic surfaces, which compounds the corrosion problem. Generally, corrosion problems are organized into the following categories: uniform corrosion; galvanic corrosion, and localized corrosion (including, crevice corrosion, pitting corrosion, etc.) [17]. The factors that contribute to corrosion are: the substrate (metallic) material and its surface structure and composition; the influence of a barrier coating, its processing conditions and/or adhesion promotion; the cleanliness of the surface, adhesion between a coating and the surface, solution concentration, solution components (especially impurities and/or oxidizers); localized geometry and applied potential. In addition, galvanic corrosion is influenced by specific metal–to–metal connections. Freescale Semiconductor, Inc. For More Information On This Product, Go to: www.freescale.com |
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